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The Solid-State Energy Storage Dam Is About to Bust Wide Open

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New solid state lithium-ion energy storage technology is still in the R&D phase, and it has already attracted EV manufacturers who love the idea of packing more muscle into smaller spaces while saving on weight, improving performance, and enhancing their safety profile, too. Now it looks like the stationary storage field is also coming over to the solid-state side, too.

QuantumScape Is On A Solid-State Energy Storage Tear

For those of you new to the topic, conventional lithium-ion batteries are based on a liquid electrolyte, which can be a bit testy unless properly engineered.

One emerging solution is to ditch the liquid electrolyte altogether in favor of a solid material, such as a specialized ceramic. The solid-state approach is also a tricky one, but one of the scientists pursuing the solid-state unicorn is famed University of Texas researcher John Goodenough, who is widely credited with inventing the rechargeable lithium-ion technology of today, and that is a pretty good indicator of the quality of the research in that direction.

Solid-state battery materials were a known thing by the early 19th century, but commercial interest in solid-state batteries didn’t really pick up a head of steam until 2020, when the idea took off like a rocket in the electric vehicle field.

The solid-state battery firm QuantumScape currently cites relationships with three automakers, including Volkswagen Group. The two companies began collaborating on solid-state EV batteries in 2015.

They have upped the ante since then, with plans in the works for a pilot manufacturing facility in Germany. In a recent letter to shareholders, QauntumScape described the battery manufacturing plan and issued a progress report on its four-layer solid-state cells, with each layer consisting of “a cathode, a solid-state separator, and an in-situ formed lithium-metal anode.”

Next Steps For Solid-State Energy Storage

QauntumScape is not letting the energy storage grass grow under its feet. Last week the company announced an agreement with the leading energy technology company Fluence, which is the first non-automotive partnership for its lithium-metal battery technology.

That’s a significant development, considering that as recently as last summer the market analyst IDTechEx was assuming that electric vehicles would lead the demand for solid-state batteries, followed by smart phones. Stationary storage could skip right over both of their heads in short order.

“The strategic relationship brings together two companies leading in technology innovation focused on accelerating clean energy adoption and reducing global carbon emissions,” QuantumScape enthuses. “The companies will collaborate on what they believe to be a first-of-its-kind solution to incorporate QuantumScape’s battery technology into Fluence stationary energy storage products as specific technical and commercial milestones are met.”

The two firms are eyeballing a hot growth rate for stationary energy storage in the coming years. Fluence already has a track record in deploying energy storage to improve transmission networks and replace new gas peaker plants, so look for the partners to zero in on those areas as well as others.

As a partner company that links Siemens and the utility AES, Fluence is in a good position to speed those lithium-metal batteries to market whenever they come rolling off the assembly line.

More Solid-State Batteries For More EVs

Meanwhile, last spring Ford and BMW also hooked up to the solid-state battery train last year. Mercedes-Benz and Stellantis caught the solid-state bug, too. GM dropped a hint about its future solid-state battery ambitions last month when it formed a partnership with the Korean firm POSCO Chemical. Toyota and Hyundai are also reported to be on board.

That’s an awfully big field of energy storage players scrambling for technology that probably won’t hit the market until 2025. However, it does give the R&D folks time to work out any remaining kinks.

One especially interesting development recently popped up in a study published in the journal Nature, which describes a “a class of elastomeric solid-state electrolytes with a three-dimensional interconnected plastic crystal phase.” The new electrolytes demonstrate “a combination of mechanical robustness, high ionic conductivity, low interfacial resistance and high lithium-ion transference number” along with “a powerful strategy for enabling stable operation of high-energy, solid-state lithium batteries.”

The research is a collaboration between the Korea Advanced Institute of Science and Technology and the Georgia Institute of Technology.

In a press release on the new study, GIT explains that elastomers are common synthetic rubbers. Rubber is not the first material that comes to mind when the topic turns to next-generation energy storage materials, but the research team gave their elastomer a high tech twist that transformed it into a “superhighway for fast lithium-ion transport with superior mechanical toughness, resulting in longer charging batteries that can go farther.”

“The key breakthrough was allowing the material to form a three-dimensional interconnected plastic crystal phase within the robust rubber matrix. This unique structure has resulted in high ionic conductivity, superior mechanical properties and electrochemical stability,” explains GIT.

The new electrolytes prevent the lithium dendrite growth that bedevils their liquid counterparts. GIT also notes that fabricating the new electrolyte is a relatively simple, low temperature process that yields a high quality result.

But…What About The Lithium?

Yes, what about it? EV supply chain observers have been watching the lithium supply chain like a hawk. The general consensus is that there needs to be a serious uptick in availability as the energy storage market takes off.

Solid-state technology can assist, partly by introducing more robust batteries with a longer lifecycle, and by decluttering the recycling pathway. However, the global lithium supply chain still has to pump itself up as the demand for batteries accelerates.

Lithium mining and brine extraction are two solutions at hand, but they can easily run afoul of environmental and cultural preservation goals. A more promising area of lithium R&D is geothermal extraction without the use of large evaporation lagoons.

Last June our friends over at the US Department of Energy produced a blueprint for lithium supply in the US and noted that “The worldwide lithium-battery market is expected to grow by a factor of 5 to 10 in the next decade.”

“The U.S. industrial base must be positioned to respond to this vast increase in market demand that otherwise will likely benefit well-resourced and supported competitors in Asia and Europe,” they added.

Game on!

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Original Article: cleantechnica.com

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